Another step forward for green chemistry
The findings, published March 27 in the journal Science Advances, could lead to a variety of possible applications in the chemical industry. The results also promise to advance the search for more environmentally friendly chemical conversion reactions using air as a green oxidant, said Chao-Jun Li, senior author of the paper and Canada Research Chair in Green Chemistry at 捆绑SM社区.
For the past two decades, researchers at 捆绑SM社区 and elsewhere have been exploring ways to do away with chemists鈥 traditional reliance on non-renewable petrochemical feedstocks, less efficient chemical transformations and toxic solvents. One important method has involved using water as a solvent.
The other authors of the new paper are Mingxin Liu, Haining Wang and Huiying Zeng, also of 捆绑SM社区鈥檚 Department of Chemistry.
The research was supported by the Canada Research Chairs program, the Canada Foundation for Innovation, Le Fonds de recherche du Qu茅bec 鈥 Nature et technologies, and the Natural Sciences and Engineering Research Council of Canada.
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鈥淪ilver(I) as a widely applicable, homogeneous catalyst for aerobic oxidation of aldehydes toward carboxylic acids in water鈥斺榮ilver mirror鈥: From stoichiometric to catalytic鈥, Mingxin Liu et al, Science Advances, 27 March 2015. 10.1126/sciadv.1500020
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